Yes.
I personally prefer Marvell-based https://shop.allnetchina.cn/collections/rock-pi-4-accessories/products/m-2-pci-e-protocol-to-4x-sata3-0-expansion , out of stock on Allnet but can be sourced on Aliexpress.
You can add 2x such cards to Rock Pi 3A/3B with the help of appropriate m.2 risers. E.g. unless you’re mounting 3B sideways, you’ll want to use https://www.ebay.com/itm/323960733359 for bottom slot.
You can also use full-size PCIe cards with more SATA ports with this adapter https://shop.allnetchina.cn/collections/rock-pi-4-accessories/products/m-2-to-pcie-x4-adapter , will end up cheaper if physical space is not a concern.